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1. ⇒  (MHT CET 2023 12th May Morning Shift )

Identify substrate A in the following reaction.

A + AgOH  i) moist  Ag 2 O ii )   Δ CH 3 CH 2   N ( CH 3 ) 2 + CH 2 = CH 2

A. Diethyldimethyl ammonium halide

B. Ethyltrimethyl ammonium halide

C. Diethyldimethyl ammonium hydroxide

D. Ethyltrimethyl ammonium hydroxide

Correct Option is (A)

The reaction is Hofmann elimination and substrate ' A ' is diethyldimethyl ammonium halide.

MHT CET 2023 12th May Morning Shift Chemistry - Compounds Containing Nitrogen Question 1 English Explanation

2. ⇒  (MHT CET 2023 10th May Evening Shift )

Identify ' A ' in the following reaction:

A ether LiAl H 4 Ethanamine

A. C 2 H 5 CN

B. CH 3 CONH 2

C. C 2 H 5 CONH 2

D. CH 3 NO 2

Correct Option is (B)

C H 3 CON H 2 ether LiAl H 4 C H 3 C H 2 N H 2 Ethana min e

3. ⇒  (MHT CET 2021 20th September Morning Shift )

What is the number of moles of H atoms required to prepare one mole ethylamine from one mole acetamide?

A. 2

B. 4

C. 3

D. 1

Correct Option is (B)

MHT CET 2021 20th September Morning Shift Chemistry - Compounds Containing Nitrogen Question 21 English Explanation

4. ⇒  (MHT CET 2021 20th September Morning Shift )

Which among following statements is NOT true about Gabriel phthalimide synthesis?

A. In this method formation of N-alkyl phthalimide is involved.

B. In this method sodium phthalate is also obtained.

C. This method is useful for preparation of aromatic amines.

D. In this method potassium salt of phthalimide is formed as an intermediate product.

Correct Option is (C)

Aromatic amines cannot be prepared by Gabriel phthalimide synthesis because aryl halides do not undergo nucleophilic substitution with the anion formed by phthalimide.