⇒Amines

1. ⇒  (MHT CET 2023 12th May Evening Shift )

Identify product $\mathrm{B}$ in the following reaction.

A. Chlorobenzene

B. Benzyl alcohol

C. Benzenediazoniumchloride

D. Phenol

2. ⇒  (MHT CET 2023 11th May Evening Shift )

If, Aniline $\frac{\text{ i) }{\mathrm{NaNO}}_2+\mathrm{HCl},273\mathrm{K}}{\text{ ii) }{\mathrm{H}}_2\mathrm{O},\mathrm{\Delta }}$ Product.

Identify the product of above reaction.

A. o-Nitroaniline

B. m-Nitroaniline

C. p-Nitroaniline

D. Phenol

3. ⇒  (MHT CET 2023 11th May Evening Shift )

Identify '$\mathrm{A}$' and '$\mathrm{B}$' in the following reaction.

${\mathrm{CH}}_3\mathrm{Br}\stackrel{{\mathrm{AgNO}}_2}{⟶}\mathrm{A}\stackrel{\mathrm{Sn}/\mathrm{HCl}}{⟶}\mathrm{B}$

A. ${\mathrm{CH}}_3{\mathrm{NO}}_2$ and ${\mathrm{CH}}_3\mathrm{Cl}$

B. ${\mathrm{CH}}_3{\mathrm{NO}}_2$ and ${\mathrm{CH}}_3{\mathrm{NH}}_2$

C. ${\mathrm{CH}}_3{\mathrm{NH}}_2$ and ${\mathrm{CH}}_3\mathrm{Cl}$

D. ${\mathrm{CH}}_3{\mathrm{NH}}_2$ and ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NO}}_2$

4. ⇒  (MHT CET 2023 11th May Morning Shift )

Benzonitrile on reduction with stannous chloride in presence of hydrochloric acid followed by acid hydrolysis forms:

A. Benzal chloride

B. Benzoyl chloride

C. Benzophenone

D. Benzaldehyde

5. ⇒  (MHT CET 2023 10th May Evening Shift )

Identify the product obtained when benzonitrile is reduced by stannous chloride in presence of hydrochloric acid followed by acid hydrolysis.

A. Benzal chloride

B. Benzoyl chloride

C. Benzophenone

D. Benzaldehyde