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Topic 01: First Law of Thermodynamic

1. ⇒ (NEET 2018 )

A sample of 0.1 g of water at 100°C and normal pressure (1.013 × 105 N m–2) requires 54 cal of heat energy to convert to steam at 100°C. If the volume of the steam produced is 167.1 cc, the change in internal energy of the sample, is

(A) 104.3 J

(B) 208.7 J

(C) 42.2 J

(D) 84.5 J

Correct answer is (B)

Using first law of thermodynamics,

Δ Q = Δ U + Δ W

54 × 4.18 = Δ U + 1.013 × 105(167.1 × 10–6 – 0)

Δ U = 208.7 J

2. ⇒ (AIPMT 2015 Cancelled Paper )

Figure below shows two paths that may be taken by a gas to go from a state A to a state C.

AIPMT 2015 Cancelled Paper Physics - Heat and Thermodynamics Question 59 English
In process AB, 400 J of heat is added to the system and in process BC, 100 J of heat is added to the system. The heat absorbed by the system in the process AC will be

(A) 460 J

(B) 300 J

(C) 380 J

(D) 500 J

Correct answer is (A)

AIPMT 2015 Cancelled Paper Physics - Heat and Thermodynamics Question 59 English Explanation
Considering the cyclic process ABCA
Qcyclic = W = area of Δ ABC

Q A B + Q B C + Q C A = 1 2 × B C × A B

400 + 100 + Q C A = 1 2 × ( 2 × 10 3 ) × 4 × 10 4

400 + 100 Q A C = 40

Hence, QAC = 460 J

3. ⇒ (AIPMT 2014 )

A thermodynamic system undergoes cyclic process ABCDA as shown in figure. The work done by the system in the cycle is

AIPMT 2014 Physics - Heat and Thermodynamics Question 57 English

(A) P0V0

(B) 2P0V0

(C) P 0 V 0 2

(D) zero

Correct answer is (D)

AIPMT 2014 Physics - Heat and Thermodynamics Question 57 English Explanation In a cyclic process work done is equal to the area under the cycle and is positive if the cycle is clockwise and negative if anticlockwise. As is clear from figure,

W A E D A = + a r e a o f Δ A E D = + 1 2 P 0 V 0

W B C E B = a r e a o f Δ B C E = 1 2 P 0 V 0

The net work done by the system is

W n e t = W A E D A + W B C E B

= + 1 2 P 0 V 0 1 2 P 0 V 0 = 0

4. ⇒ (NEET 2013 (Karnataka) )

A system is taken from state a to state c by two paths adc and abc as shown in the figure. The internal energy at a is U a = 10 J . Along the path adc the amount of heat absorbed dQ1 = 50 J and the work obtained dW1 = 20 J whereas along the path abc the heat absorbed dQ2 = 36 J. The amount of work allong the path abc is

NEET 2013 (Karnataka) Physics - Heat and Thermodynamics Question 51 English

(A) 10 J

(B) 12 J

(C) 36 J

(D) 6 J

Correct answer is (D)

From first law of thermodynamics

Q a d c = Δ U a d c + W a d c

50 J = Δ U a d c + 20 J

Δ U a d c = 30 J

Again

Q a b c = Δ U a b c + W a b c

W a b c = Q a b c Δ U a b c

W a b c = 36 J 30 J

W a b c = 6 J

5. ⇒ (NEET 2013 )

The amount of heat energy required to raise the temperature of 1 g of Helium at NTP, from T1K to T2K is

(A) 3 4 N a k B ( T 2 T 1 )

(B) 3 4 N a k B ( T 2 T 1 )

(C) 3 8 N a k B ( T 2 T 1 )

(D) 3 2 N a k B ( T 2 T 1 )

Correct answer is (C)

From first law of thermodynamics

Δ Q = Δ U + Δ W = 3 2 . 1 4 R ( T 2 T 1 ) + 0

= 3 8 N a K B ( T 2 T 1 )      [ K = R N ]

6. ⇒ (NEET 2013 )

A gas is taken through the cycle
A B C A, as shown. what is the net work done by the gas?

NEET 2013 Physics - Heat and Thermodynamics Question 54 English

(A) Zero

(B) 2000 J

(C) 2000 J

(D) 1000 J

Correct answer is (D)

Wnet = Area of triangle ABC

= 1 2 A C × B C

= 1 2 × 5 × 10 3 × 4 × 10 5 = 1000 J

7. ⇒ (AIPMT 2012 Mains )

An ideal gas goes from state A to state B via three different processes as indicated in the P-V diagram.

AIPMT 2012 Mains Physics - Heat and Thermodynamics Question 46 English

If Q1, Q2, Q3 indicate the heat absorbed by the gas along the three processes and Δ U1, Δ U2, Δ U3 indicate the change in internal energy along the three processes respectively, then

(A) Q1 > Q2 > Q3 and Δ U1 = Δ U2 = Δ U3

(B) Q3 > Q2 > Q1 and Δ U1 = Δ U2 = Δ U3

(C) Q1 = Q2 = Q3 and Δ U1 > Δ U2 > Δ U3

(D) Q3 = Q2 = Q1 and Δ U1 > Δ U2 > Δ U3

Correct answer is (A)

Initial and final condition is same for all process

Δ U 1 = Δ U 2 = Δ U 3

from first law of thermodynamics

Δ Q = Δ U + Δ W

Work done

Δ W 1 > Δ W 2 > Δ W 3    (Area of P.V. graph)

So Δ Q 1 > Δ Q 2 > Δ Q 3

8. ⇒ (AIPMT 2012 Prelims )

A thermodynamic system is taken through the cycle ABCD as shown in figure. Heat rejected by the gas during the cycle is

AIPMT 2012 Prelims Physics - Heat and Thermodynamics Question 23 English

(A) 2PV

(B) 4PV

(C) 1 2 PV

(D) PV

Correct answer is (A)

AIPMT 2012 Prelims Physics - Heat and Thermodynamics Question 23 English Explanation
In a cyclic process,

Δ U = 0

In a cyclic process work done is equal to the area under the cycle and is positive if the cycle is clockwise and negative if anticlockwise.

Δ W = – Area of rectangle ABCD = – P(2V) = – 2PV

According to first law of thermodynamics

Δ Q = Δ U + Δ W Δ Q = Δ W
    (As Δ U = 0 )

i.e., heat supplied to the system is equal to the work done

So heat absorbed, Δ Q = Δ W = – 2PV

Heat rejected by the gas = 2PV

9. ⇒ (AIPMT 2009 )

The internal energy change in a system that has absorbed 2 kcal of heat and done 500 J of work is

(A) 6400 J

(B) 5400 J

(C) 7900 J

(D) 8900 J

Correct answer is (C)

When a quantity Q of heat is supplied to a system it is used to do an amount of work W by the system and to increase the internal energy of the system by ∆U :

Q = ∆U + W

Here, Q given in kilo calories is converted into joule.
Therefore Q = 2×1000×4.2 J = 8400 J

The increase the internal energy

∆U = Q – W = 8400 – 500 = 7900 J